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Cobalt Oxide  (Co3O4)--Low Sodium Electronic Grade
 

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Specification

Assay (As Co) 72.5% minimum
Sulfer 40 ppm maximum
Chromium (Cr) 20 ppm maximum
Calcium (Ca) 3 ppm maximum
Copper (Cu) 5 ppm maximum
Iron (Fe) 100 ppm maximum
Magnesium (Mg) 100 ppm maximum
Manganese (Mg) 30 ppm maximum
Nickel (Ni) 50 ppm maximum
Sodium (Na) 50 ppm maximum
Zinc (Zn) 3 ppm maximum
Average particle size, d50, in microns: 2.0 Typical

Cobalt oxide is derived from cobalt, a ferromagnetic metal used in various alloy forms for their heat resistance and magnetic properties. Cobalt is a fairly rare metal, comprising only 0.001 percent of the earth's crust, but is widely dispersed and commonly found and obtained in association with other mining activities. It is found in ores of iron, nickel, copper, silver, manganese, zinc and arsenic. Alloys of cobalt are useful for their stability at high temperatures. Superalloys are used near their melting points, where steel would become too soft. Cobalt is used as a hardener (eg., for tools), for glass to metal seals (where its low-expansion is an advantage), and precision springs (where its elasticity is an advantage),

Historical Background

Cobalt was isolated in 1735 by Georg Brandt, although compounds containing cobalt have been used for thousands of years. It has been detected in ancient Egyptian statuettes and ancient Chinese pottery. Cobalt was first named in the 16th century when found in arsenic ores, thought to be copper ores, but which because of their arsenic content were poisonous.

Cobalt Oxide

Cobalt oxide is used in two covalent states, CoO and Co
3O4. The latter form is the most commonly used in manufacturing ceramics, glass and enamels, and in preparing catalysts and cobalt metal powder. In combination with lead, cobalt oxide provides a brillian blue glaze on ceramics--which explains the scare about blue ceramics several years ago. It is prepared by heating cobaltus hydroxide or oxide in air at 100 degrees centigrade. At lower temperatures oxygen may be absorbed while leaving the crystal structure unchanged. At temperatures above 900 degrees centigrade, oxygen is lost, and cobalt moxoxide is formed. Like the other oxides of cobalt, the tetroxide form reduces to the metal when heated in hydrogen.

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